UV degradation
Introduction
Photodegradation is the alteration of materials due to the effect of light. Normally the term refers to the combined action of sunlight and the Earth's atmosphere. Photodegradation is usually a combination of oxidation and hydrolysis. An attempt is often made (through coatings, additives, etc.) to avoid photodegradation of objects that are going to be outdoors, because otherwise they will be damaged and must be replaced. This phenomenon is partly responsible for the remineralization of biomass, and is intentionally used in some disinfection technologies. Photodegradation does not apply to how materials can be aged or degraded by heat or infrared radiation, but does include degradation by all light radiation in the ultraviolet band.
Applications
Food
Protecting food from photodegradation is very important. Some nutrients present in a food degrade when it is exposed to the sun. In the case of beer, ultraviolet radiation degrades hop bitter compounds to 3-methyl-2-buten-1-thiol, thereby changing the flavor. As amber glass has the ability to absorb this radiation, beer bottles are often made from this glass to prevent this change.
Paints, inks and dyes
Organic paints, inks and dyes are more susceptible to photodegradation than inorganic ones. Ceramics are almost universally colored with inorganic materials so that they resist photodegradation and maintain their colors even in the harshest conditions.
Pesticides and herbicides
The photodegradation of pesticides is of great interest due to the scale of agriculture and the intensive use of chemicals. Pesticides are chosen in part so as not to rapidly photodegrade in the sun, and thus be able to exert their biocidal activity. However, in certain circumstances, rapid photodegradation may be preferred (for example, because pesticide residues are not desired in foods that will soon be harvested). In these cases, the pesticide is formulated to promote its photodegradation with substances that are very sensitive to light, photocatalysts (e.g., titanium dioxide "Titanium (IV) Oxide")), or reagents such as hydrogen peroxide, which generates hydroxyl radicals that attack the pesticide molecules.[1].