Groundwater pollution
Groundwater is water that exists underground within saturated zones beneath the Earth's surface. Fills pores, fractures and cracks in underground geological materials such as sand, gravel and rock. Groundwater is a vital natural resource, representing available freshwater resources as it serves as the primary source of drinking water.[45] Contaminants once released into the soil generally move downward through the soil profile. The soil acts as a filter for larger particles, but many dissolved chemicals, fine particles, and various man-made substances can pass into the aquifer and descend to the ground.[46].
Groundwater contamination at Superfund sites is the result of the release of hazardous substances from various industrial activities and waste disposal practices. The characterization of Superfund sites means that it is a complex mixture of contaminants rather than a single contaminant.[47] These substances can be transported from the original source through the soil to underlying aquifers, which could create a persistent environment and cause potential health risks. Superfund sites generally originate from past industrial operations where hazardous substances were manufactured, used or disposed of, with practices that would be considered inadequate or illegal by modern environmental standards.[48] Many of these sites reflect a history of unregulated industrial practices, where waste disposal methods common at the time led to direct and often extensive contamination of soil and groundwater. This historical context means that contamination is widespread, involves mixtures of contaminants, and is deeply embedded in the soil, making cleanup inherently more complex and costly. The varied industrial histories of Superfund sites have resulted in a wide variety of contaminants contaminating groundwater.[49] The fact that these contaminants are persistent means that they do not break down in the environment as easily. Such mixtures can cause toxic effects on humans and ecosystems and make remediation considerably more difficult, as technologies effective for one contaminant may be ineffective or even counterproductive for another. Some of the most common contaminants include: Lead (43% of sites), trichlorethylene (42%), chromium (35%), benzene (34%), perchlorethylene (28%), arsenic (28%), and toluene (27%) (ATSDR, 1989).[50].
Key industrial activities and sources contributing to groundwater contamination at Superfund sites include:[51].
• - Chemical Manufacturing and Production: Facilities involved in the manufacturing of chemicals, pesticides, pharmaceuticals, plastics and other goods have often been sources of pollution through improper disposal of process waste, accidental spills or leaks of solvents, pesticides and various industrial chemicals. These pollutants often include persistent organic pollutants.
• - Mining and Metal Processing: Mining operations and metal processing facilities can release heavy metals such as lead, arsenic and mercury into the environment. Acid mine drainage, a highly acidic, metal-laden discharge from certain types of mines, is a particularly serious form of water pollution. Many legacy mining operations, which ceased activity before the advent of modern environmental regulations, have left extensive soil and water contamination.
• - Petroleum refining and storage: Leaks and spills of crude oil, gasoline, diesel fuel, and other petroleum products can contaminate soil and groundwater with hazardous substances such as benzene. Underground storage tanks (UST) used to store petroleum products at gas stations and industrial facilities are a common source of leaks.
• - Waste Management and Landfills: Landfills, particularly older ones built before strict design and operational regulations were implemented, are major sources of groundwater contamination. Hazardous waste discarded at these landfills can leach as rainwater percolates through the waste, forming a contaminated liquid called leachate. If the landfill lacks adequate liners and leachate collection systems, leachate can migrate into the underlying soil and groundwater.
• - Military and Defense-related Activities: Numerous military bases and defense-related facilities have become Superfund sites due to contamination from activities such as weapons testing and maintenance, aircraft and vehicle maintenance, and waste disposal. Common contaminants include explosives, solvents (such as TCE used for degreasing), fuels, and in some cases, radioactive materials.
• - Agricultural practices: Although less frequently the primary driver of a Superfund designation compared to industrial sites, agricultural activities can contribute to groundwater contamination through the widespread use of pesticides and fertilizers. Runoff from agricultural fields can carry these chemicals into surface waters and also allow them to leach into groundwater.
Contamination of groundwater resources by hazardous substances released from Superfund sites has consequences that affect human health. Humans can be exposed to contaminants present in groundwater through multiple pathways, not just through direct consumption of drinking water.[52] This multiplicity of exposure pathways means that simply providing an alternative source of drinking water may not eliminate all health risks if other pathways are not appropriately evaluated and managed. The specific health risks associated with exposure to contaminated groundwater depend on several factors, including the types and concentrations of contaminants present.[53] Toxicity is the most common concern regarding groundwater contaminants. Toxicity is classified as acute or chronic. Acute toxicity results from short-term exposure to relatively high doses of contaminants and chronic toxicity occurs as a result of drinking low concentrations of contaminants over a long period of time. Chronic toxicity is the most common toxicity in groundwater contamination that comes from improper disposal of hazardous chemicals.[50].
Common health effects related to contaminants frequently found at Superfund sites include:[54].
• - Microorganisms: They can cause gastrointestinal diseases and infections.
• - Nitrates and nitrites: High levels can cause methemoglobinemia ("blue baby syndrome") in babies, a serious condition that affects the blood's ability to carry oxygen.
• - Heavy metals (e.g., lead, arsenic, cadmium, mercury): They can cause a wide range of health problems, including acute and chronic toxicity, liver, kidney and intestinal damage, anemia, neurological damage, developmental problems and several types of cancer.
• - Organic chemicals (e.g., volatile organic compounds, pesticides): Associated with damage to the kidneys, liver, circulatory system, nervous system, and reproductive system. Many are known or suspected carcinogens.
Groundwater contamination from Superfund sites does not remain isolated beneath the ground. As groundwater moves, it can be discharged into surface water bodies such as rivers, lakes, streams, and wetlands.[55] Pollution is removed from the original source of pollution at the Superfund site and continues to other areas. Contaminated groundwater can play a factor in many environmental and ecological areas.[56].
Effects of the introduction of dangerous substances:[57].
• - Direct toxicity to aquatic life: Many contaminants are directly toxic to fish, amphibians and aquatic plants. Exposure can lead to mortality, reduced growth and reproductive success, physiological stress, or chronic health problems.
• - Bioaccumulation and biomagnification: Persistent contaminants, such as heavy metals and certain organic contaminants, can accumulate in your tissues over time. As these organisms are consumed by predators, the concentration of these toxins can increase at successively higher levels of the food chain, potentially reaching levels that are harmful to wildlife and humans who consume these contaminated fish.
• - Habitat Degradation: The influx of pollutants can alter the chemical composition of surface water, such as changing pH and sediment, making habitats unsuitable for many native aquatic species. This can lead to a decrease in species richness and abundance.
• - Loss of biodiversity: The overall biodiversity of the aquatic ecosystem can be reduced. This can upset the ecological balance and affect the ecosystem's ability to perform essential functions, such as nutrient cycling and water purification.
• - Eutrophication and Oxygen Depletion: Over-enrichment of nutrients that feeds the excessive growth of algae and aquatic plants (algal blooms). When these flowers die and decompose, bacteria consume large amounts of dissolved oxygen in the water, leading to dead zones that can suffocate fish and other oxygen-dependent aquatic life.
• - Soil Pollution: The accumulation of heavy metals, persistent organic pollutants or other toxins in soil can reduce soil fertility and damage soil microorganisms essential for nutrient cycling.
• - Vegetation Impacts: Plants can absorb contaminants from soil or water, resulting in reduced growth, visible injury, or death. Contaminants can also accumulate in plant tissues, potentially entering terrestrial food webs.