Hygroscopic cycle
Introduction
The Hygroscopic Cycle is a thermodynamic cycle, similar to the Rankine cycle, characterized by working "Work (physics)") with hygroscopic compounds which optimize the condensation "Condensation (change of state)") of the turbine exit steam, being able to work with high vacuum at the turbine exit and good cooling conditions. In short, the condensation temperature "Condensation (change of state)") is increased for a given pressure in the condenser "Condenser (thermodynamics)").
In this cycle the condenser "Condenser (thermodynamics)") is a vapor absorber, unlike the traditional condenser "Condenser (thermodynamics)") found in the Rankine cycle. Here the turbine output steam is absorbed by an aqueous stream rich in hygroscopic compounds, which in addition to providing their physical and chemical properties to the process, protect the cycle from corrosion, adjust the pH, and control scale. The condensation energy "Condensation (change of state)") of this cycle is released in an air cooler so that the consumption of cooling water in most cases is practically zero.
In this cycle, the boiler purge rich in hygroscopic compounds is used, both thermally in an enthalpic recuperator, and chemically #solubility_of_gases_in_liquids "Absorption (chemical)") in a steam absorber.
The configuration of this cycle, the use of hygroscopic compounds and its characteristic equipment (vapor absorber, aerorefrigerant and enthalpic recovery) allow it to provide, unlike a Rankine cycle, greater electrical performance, savings of 85 to 100% in cooling water, reduction in investment price, reduction in operation and maintenance costs, longer life of the installation, reliability, availability and reduction of environmental impact.[1][2].
Beginning
Absorption cycles are physically based on the ability of some substances, such as water and some salts such as lithium bromide, to absorb, in the liquid phase, vapors of other substances such as ammonia and water, respectively. By similarity, in this cycle water would be the cooling fluid and the hygroscopic compound the absorbent.
One of the main applications of hygroscopic compounds is absorption refrigeration. These machines began to be marketed in the early 1950s, although their principle has been known for more than 100 years.